I would like to minimize case expansion possibly leading to more concentricty of bullet seat to throat brass working etc.
Not quite a sentence.
In some respects, Al and his experience runs counter to others of us. But it is still experience.
Part 1: As far as case head expansion -- you cannot minimize any expansion of the case that is beyond the chamber -- there is no steel "containing" it. This is usually what is thought of as the "case head." But you can minimize expansion just ahead of the web, where the case is supported. Let's suppose you decide a chamber of .003 over body diameter is right. So, you measure a Lapua case, then buy Norma or RWS brass. Guess what -- they likely have slightly different body diameters, at least, for a number of cases. Norma 6PPC cases run about .003 smaller than Lapua .220 Russian cases. I've forgotten which is which, but Steve Shelp got Norma, Lapua, and RWS 6.5x55 cases. Differences in body diameter were significant.
So, buy your brass before ordering your reamer. Either mike it carefully, or if you cannot, send a case to the reamer manufacturer along with your wishes for clearance.
Part 2: As far as centering the bullet in the bore, read T.J. Jackson's article in
Precision Shooting, October, 1985. Well, you don't have it to hand. Essentially, he proved, by shooting in the Houston Warehouse, that if the case necks were true to the bore centerline, and the case head was square to the bore (really, the boltface, which better be 90 degrees true to the bore), the rest of the case was irrelevant. Now most of us can't machine a case like T.J. did, but it does show that excessively tight chambers aren't the answer, good necks are -- and square case heads.