Chrome-lined barrels...
are, indeed, plated with hard industrial chromium.
The process requires an electrode of a form which is the reverse of the rifled bore, in order to prevent plating of uneven thickness caused by varying distance from the electrode to the bore surface - needless to say the quality of the plating depends on accurate orientation and centering of the electrode in the bore. It is also necessary to dimension the finish-rifled bore to allow for the thickness of plating while remaining within permissible tolerances.
Others have given the reasons why such plating is useful in military barrels: these hardly apply to civilian use, since civilians do not (usually) subject their arms to the extremes of environment experienced in military hands, nor do they often engage in extended periods of rapid fire or full-auto fire.
Examination of the interior of plated barrels will show that the surface finish is usually not so good as in an un-plated bore: neither is the average accuracy. When chromed barrels DO fail, they usually do so by cracking and flaking-off of the plating in the throat, extending progressively forward with further use: when this happens, that barrel is done, so far as accuracy goes.
If your requirement is for best accuracy, rather than endurance of extreme conditions, a non-plated barrel is the best choice.
mhb - Mike