Russell,
Changes in air density makes our rifles to go out of tune. If the bullets are exiting when the barrel is stopped at either the top or bottom of the swing, the rifle is in tune. If the atmosphere becomes less dense due to an increase in temperature, the bullet encounters less resistance as it travels down the bore and exits early before the barrel comes to a complete stop, in which case, we can either reduce the load or adjust the tuner to compensate. I think it's much simpler and easier to use a tuner. You NEVER have to change the load and can make your adjustments at the line.
Atmospheric density is the result of pressure altitude, temperature and to a far lesser degree, moisture content. Contrary to what many believe, dry air is heavier. Steam rises and it's 100 percent saturated.
So,, altitude, temp and humidity in that order. What do we mean by altitude? Range elevation above sea level. The Midland Shooters Association range is 2800 feet above sea level; that never changes so we can forget about it. Yes, slight variations in barametric pressure can change the pressure altitude but for all practical purposes, we can forget about it.
Temperature? This is the big one! It's actually the only thing you must concern yourself with. The temperature range from being perfectly in tune and being completely out is 20 degrees F.
Yep, if your rifle is perfectly in tune during the first match of the day when temperature is 70 it will be completely out of tune when the temp reaches 90 if you do nothing to compensate.
To keep the rifle in tune throughout the day, reduce the velocity 30 fps for each five degree increase in temp. With most powders, N133 being the classic example, this equates to one half click per five degrees. For example, let's say your rifle was in tune for the first match; temp was 70. Your Culver type measure was set on 54 clicks. When temp reaches 75 the proper click value is 53.5, for 80, 53, 75, 52.5 and for 90F, 52 clicks. Would you have ever believed it would take two full numbers to stay in tune with a twenty degree spread?
"Now wait a minute Beggs; are you telling me relative humidity has nothing to do with it?" Yep, that's right; very little, so little that for all practical purposes we can ignore it.
Relative humidity (RH) is expressed in percent of saturation at a given temperature. If RH is reported as 30%, temp 85 degrees, this means the air contains thirty percent of the moisture it is capable of holding at that temperature. If temp goes up, RH goes down and vice versa even though the amount of moisture in the air is exactly the same.
Some shooters say they adjust the powder charge by relative humidity; RH goes down, they go down on the load and vice versa insisting it is humidity that affects the rifle's tune when in fact it is the change in temperature that is actually responsible.
And BTW, you asked if changes in conditions affects barrel harmonics?" NO
Hope this helps
Later,
Gene Beggs